% used options: used options: -w -t 2 (no cross bond) \chemfig{ % 1 -[,1.414]% 2 -[:225,2]% 4 -[,1.414]% 3 ( -[:135,2]% -> 1 ) } % added option: --cross-bond 2-4 \chemfig{ % 1 -[,1.414]% 2 -[:225,2,,,draw=none]% 4 bond 2 -> 4 is not rendered at first -[,1.414]% 3 ( -[:135,2]% -> 1 ) (% append cross bond to end of molecule -[:90,1.414,,,draw=none]% -> 2 - invisible bond moves the pen to atom 2 -[:225,2,,,mcfcrossbond]% -> 4 - the cross bond is rendered, applying )% the mcfcrossbond tikz key }